聚驱用疏水缔合聚合物AP-P4油水固三相与水固两相差异性实验研究

李如茵; 檀国荣; 张健

高级检索

E-mail Alert

聚驱用疏水缔合聚合物AP-P4油水固三相与水固两相差异性实验研究　　

李如茵, 檀国荣, 张健

文章导航 > 石油钻采工艺 > 2013 > 35(3): 80-85

李如茵, 檀国荣, 张健. 聚驱用疏水缔合聚合物AP-P4油水固三相与水固两相差异性实验研究　　[J]. 石油钻采工艺, 2013, 35(3): 80-85.

引用本文:

李如茵, 檀国荣, 张健. 聚驱用疏水缔合聚合物AP-P4油水固三相与水固两相差异性实验研究　　[J]. 石油钻采工艺, 2013, 35(3): 80-85.

LI Ruyin, TAN Guorong, ZHANG Jian. Different distribution behavior of hydrophobic associated polymer AP-P4 between oil-water-solid three-phase system and water-solid two-phase[J]. Oil Drilling & Production Technology, 2013, 35(3): 80-85.

Citation:

LI Ruyin, TAN Guorong, ZHANG Jian. Different distribution behavior of hydrophobic associated polymer AP-P4 between oil-water-solid three-phase system and water-solid two-phase[J]. Oil Drilling & Production Technology, 2013, 35(3): 80-85.

聚驱用疏水缔合聚合物AP-P4油水固三相与水固两相差异性实验研究　　

李如茵^1,2,
檀国荣^1,2,
张健^1,2

1.
海洋石油高效开发国家重点实验室，北京　100027
2.
中海油研究总院，北京　100027

详细信息

中图分类号: TE357.46

Different distribution behavior of hydrophobic associated polymer AP-P4 between oil-water-solid three-phase system and water-solid two-phase

1.
State Key Laboratory of Offshore Oil Exploitation, Beijing 100027, China
2.
Research Institute, CNOOC, Beijing 100027, China

摘要: 目前，对海上油田聚驱用疏水缔合聚合物吸附、分配行为所开展实验仅限于在水固两相体系之间，而实际油藏中有大量油相存在，尚无实验方法对聚合物在多相间的分配规律进行测试。基于静态吸附原理，建立了一套测定疏水缔合聚合物AP-P4在油、水、固三相体系间分配规律的实验方法，可以准确测定不同溶液浓度、矿化度条件下，疏水缔合聚合物在三相间的分配规律。选择精确的测试手段分别测定了水相与油相中聚合物的浓度，并与水固两相体系静态吸附结果进行了对比。实验结果表明，尽管聚合物在油相中不溶解，但油相的引入造成了疏水缔合聚合物在油水界面间出现了明显的富集现象。该方法比传统的两相静态吸附方法更全面、准确地揭示了各相间的相互作用、相互影响，有助于深化对疏水缔合聚合物溶液性质的认识，为预测实际油藏化学驱过程中的吸附滞留行为、评估采出液处理过程中乳化相含聚量提供了理论支持。
- 疏水缔合聚合物 /
- 三相体系 /
- 静态吸附 /
- 分配系数 /
- 油水界面
Abstract: Abstract：At present, the experiments aimed at studying the adsorption and distribution behavior of hydrophobic associating polymer are confined only to water-solid two-phase system in offshore oilfield. While there is a large number of oil actual existences in reservoir, and no experiment method is conducted to test the distribution behavior of hydrophobic associated polymer in multi-phase system. A set of experimental method has been established for the first time in order to evaluate the distribution of water soluble hydrophobic associated polymer AP-P4 among oil, water and sand based on the static adsorption principle. The distribution law of the AP-P4 polymer in three-phase system under different solution concentration and different salinity conditions can be accurately determinate. The suitable analysis method has been selected to measure the concentration of polymer in oil phase and water phase. By comparison with water-solid two-phase static adsorption result, it showed that the oil-water interface was enriched in hydrophobically associating polymer because of introducing oil phase even though the polymer is not dissolved in the oil phase. Comparing to the conventional two-phase static adsorption method, the newly technique can more comprehensive, more accurately reveals the interaction and mutual influence between the each phase, and contributes to deepen understanding the properties of hydrophobically associating polymer solution. The method also provides theoretical support for predicting the adsorption and retention in actual reservoir chemical flooding process, and evaluating emulsion polymer containing quantity in produced fluid treatment process.　　
- Key words：hydrophobically associating polymer /
- three-phase system /
- static adsorption /
- distribution coefficient /
- oil water contact

[1]	刘亚静, 乔宽, 李天友, 孟灵, 王开红, 邢艳辉. 光纤式油水界面仪井下损坏分析及防范措施 . 石油钻采工艺, 2020, 42(4): 523-526. doi: 10.13639/j.odpt.2020.04.026
[2]	姚金星, 万里平, 高攀明, 刘振东, 陈永斌. 聚合物纳米组装微泡沫钻井液体系及其性能评价 . 石油钻采工艺, 2018, 40(5): 577-581. doi: 10.13639/j.odpt.2018.05.008
[3]	谢彬强, 郑力会. 基于疏水缔合聚合物的新型钻井液封堵剂 . 石油钻采工艺, 2015, 37(5): 41-45. doi: 10.13639/j.odpt.2015.05.011
[4]	赖南君, 闻一平, 傅波, 徐俊芳, 王思遥, 王爱香. 复合交联聚合物弱凝胶体系的研制与性能评价 . 石油钻采工艺, 2014, 36(3): 87-91. doi: 10.13639/j.odpt.2014.03.022
[5]	宋爱莉, 孙林, 朱洪庆, 刘春祥, 夏光, 山金城. SZ36-1油田缔合聚合物驱堵塞物形成机理分析 . 石油钻采工艺, 2011, 33(1): 83-87.
[6]	冯茹森, 郭拥军, 周薇, 杨爱武. 疏水缔合聚合物流变学测量方法研究I：稳态剪切黏度 . 石油钻采工艺, 2011, 33(1): 56-60.
[7]	冯茹森, 郭拥军, 吕鑫, 王鹤, 薛新生. 疏水缔合聚合物流变学测量方法Ⅱ：零剪切黏度 . 石油钻采工艺, 2011, 33(4): 55-58.
[8]	方文超, 唐善法, 胡小冬, 陈婷婷, 单海丹, 闫双喜. 阴离子双子表面活性剂的油水界面张力研究 . 石油钻采工艺, 2010, 32(5): 86-89.
[9]	陈士佳, 黄波, 朱洪庆, 王成胜, 易飞, 孙艳萍. 疏水缔合聚合物溶液稳黏药剂评价研究 . 石油钻采工艺, 2010, 32(6): 89-92.
[10]	杨帆, 李治平, 李向齐. 凝析气藏气液固三相数值模拟 . 石油钻采工艺, 2007, 29(3): 101-104. doi: 10.3969/j.issn.1000-7393.2007.03.032
[11]	洪楚侨, 叶仲斌, 施雷庭, 张超, 杨泽超. 疏水缔合聚合物溶液特性及评价方法 . 石油钻采工艺, 2007, 29(2): 61-64. doi: 10.3969/j.issn.1000-7393.2007.02.017
[12]	杨二龙, 宋考平. 大庆油田三类油层聚合物驱注入速度研究 . 石油钻采工艺, 2006, 28(3): 45-49. doi: 10.3969/j.issn.1000-7393.2006.03.014
[13]	冯茹森, 郭拥军, 马军隆, 薛新生, 王彧, 李爱辉. 驱油用疏水缔合聚合物AP-P4在线熟化技术室内研究 . 石油钻采工艺, 2006, 28(5): 34-37,49. doi: 10.3969/j.issn.1000-7393.2006.05.012
[14]	郭拥军, 冯茹森, 马军隆, 舒政, 牛洪斌. 驱油用疏水缔合聚合物AP-P4在线熟化技术现场放大试验 . 石油钻采工艺, 2006, 28(6): 42-45. doi: 10.3969/j.issn.1000-7393.2006.06.013
[15]	周长静, 李华斌, 苏国辉, 闫志强, 吕海燕. 渤海绥中油田J3井疏水缔合聚合物驱数值模拟研究 . 石油钻采工艺, 2006, 28(5): 31-33. doi: 10.3969/j.issn.1000-7393.2006.05.011
[16]	李传乐, 何云章, 张三辉, 穆哈拜, 邵红新. 低渗油藏缔合聚合物调剖体系 . 石油钻采工艺, 2004, 26(3): 55-57. doi: 10.3969/j.issn.1000-7393.2004.03.017
[17]	王平美, 罗健辉, 张颖, 白风鸾. 用于高温高盐油田的非离子聚合物弱凝胶调驱体系 . 石油钻采工艺, 2002, 24(5): 53-55. doi: 10.3969/j.issn.1000-7393.2002.05.017
[18]	王富华, 邱正松, 冯京海, 陈永浩, 顾法钊, 梁国昌. KCl-BPS聚合物钻井液体系 . 石油钻采工艺, 2002, 24(3): 16-19. doi: 10.3969/j.issn.1000-7393.2002.03.006
[19]	王健, 罗平亚. 新型缔合聚合物调堵体系的研制 . 石油钻采工艺, 2000, 22(3): 54-56. doi: 10.3969/j.issn.1000-7393.2000.03.016
[20]	赵树栋, 赵新红. 探边测试技术在楚28断块滚动开发中的应用 . 石油钻采工艺, 1995, 17(3): 58-60,70. doi: 10.3969/j.issn.1000-7393.1995.03.013

点击查看大图

计量

文章访问数: 2711
HTML全文浏览量: 24
PDF下载量: 386
被引次数: 0

聚驱用疏水缔合聚合物AP-P4油水固三相与水固两相差异性实验研究　　

1. 海洋石油高效开发国家重点实验室，北京　100027

2. 中海油研究总院，北京　100027

收稿日期: 2019-05-22
修回日期: 2019-05-22
刊出日期: 2013-09-26

中图分类号: TE357.46

关键词:

摘要: 目前，对海上油田聚驱用疏水缔合聚合物吸附、分配行为所开展实验仅限于在水固两相体系之间，而实际油藏中有大量油相存在，尚无实验方法对聚合物在多相间的分配规律进行测试。基于静态吸附原理，建立了一套测定疏水缔合聚合物AP-P4在油、水、固三相体系间分配规律的实验方法，可以准确测定不同溶液浓度、矿化度条件下，疏水缔合聚合物在三相间的分配规律。选择精确的测试手段分别测定了水相与油相中聚合物的浓度，并与水固两相体系静态吸附结果进行了对比。实验结果表明，尽管聚合物在油相中不溶解，但油相的引入造成了疏水缔合聚合物在油水界面间出现了明显的富集现象。该方法比传统的两相静态吸附方法更全面、准确地揭示了各相间的相互作用、相互影响，有助于深化对疏水缔合聚合物溶液性质的认识，为预测实际油藏化学驱过程中的吸附滞留行为、评估采出液处理过程中乳化相含聚量提供了理论支持。

English Abstract

Different distribution behavior of hydrophobic associated polymer AP-P4 between oil-water-solid three-phase system and water-solid two-phase

1. State Key Laboratory of Offshore Oil Exploitation, Beijing 100027, China

2. Research Institute, CNOOC, Beijing 100027, China

Received Date: 2019-05-22
Rev Recd Date: 2019-05-22
Publish Date: 2013-09-26

Keywords:

Key words：hydrophobically associating polymer /
three-phase system /
static adsorption /
distribution coefficient /
oil water contact

Abstract: Abstract：At present, the experiments aimed at studying the adsorption and distribution behavior of hydrophobic associating polymer are confined only to water-solid two-phase system in offshore oilfield. While there is a large number of oil actual existences in reservoir, and no experiment method is conducted to test the distribution behavior of hydrophobic associated polymer in multi-phase system. A set of experimental method has been established for the first time in order to evaluate the distribution of water soluble hydrophobic associated polymer AP-P4 among oil, water and sand based on the static adsorption principle. The distribution law of the AP-P4 polymer in three-phase system under different solution concentration and different salinity conditions can be accurately determinate. The suitable analysis method has been selected to measure the concentration of polymer in oil phase and water phase. By comparison with water-solid two-phase static adsorption result, it showed that the oil-water interface was enriched in hydrophobically associating polymer because of introducing oil phase even though the polymer is not dissolved in the oil phase. Comparing to the conventional two-phase static adsorption method, the newly technique can more comprehensive, more accurately reveals the interaction and mutual influence between the each phase, and contributes to deepen understanding the properties of hydrophobically associating polymer solution. The method also provides theoretical support for predicting the adsorption and retention in actual reservoir chemical flooding process, and evaluating emulsion polymer containing quantity in produced fluid treatment process.　　

李如茵, 檀国荣, 张健. 聚驱用疏水缔合聚合物AP-P4油水固三相与水固两相差异性实验研究　　[J]. 石油钻采工艺, 2013, 35(3): 80-85.

引用本文:

李如茵, 檀国荣, 张健. 聚驱用疏水缔合聚合物AP-P4油水固三相与水固两相差异性实验研究　　[J]. 石油钻采工艺, 2013, 35(3): 80-85.

Citation:

LI Ruyin, TAN Guorong, ZHANG Jian. Different distribution behavior of hydrophobic associated polymer AP-P4 between oil-water-solid three-phase system and water-solid two-phase[J]. Oil Drilling & Production Technology, 2013, 35(3): 80-85.